Arrhenius Confidence Bounds

This subchapter is made up of the following topics:

Approximate Confidence Bounds for the Arrhenius Exponential

There are different methods for computing confidence bounds. ALTA utilizes confidence bounds that are based on the asymptotic theory for maximum likelihood estimates, most commonly referred to as the Fisher Matrix Bounds.

Confidence Bounds on the Mean Life

The Arrhenius-exponential distribution is given by Eqn. ( 1) by setting m = L(V) as shown in Eqn. ( 6). The upper mU and lower mL bounds on the mean life are then estimated by:

6.11.19.gif(19)

6.11.20.gif(20)

where Kα is defined by:

6.11.21.gif(21)

If delta.gif is the confidence level (i.e. 95% = 0.95), then α = 1delta2.gif for the two-sided bounds, and α = 1 - delta.gif for the one-sided bounds. The variance of mhat.gif is given by:

6.11.0.gif

or:

6.11.22.gif(22)

The variances and covariance of B and C are estimated from the local Fisher Matrix (evaluated at bhat.gif, chat.gif) as follows:

6.11.23.gif(23)

Confidence Bounds on Reliability

The bounds on reliability for any given time, T, are estimated by:

6.12.1.gif

where mU and mL are estimated using Eqns. ( 19) and ( 20).

Confidence Bounds on Time

The bounds on time (ML estimate of time) for a given reliability are estimated by first solving the reliability function with respect to time:

6.13.1.gif

The corresponding confidence bounds are then estimated from:

6.13.2.gif

where mU and mL are estimated using Eqns. ( 19) and ( 20).

Approximate Confidence Bounds for the Arrhenius Weibull

Bounds on the Parameters

From the asymptotically normal property of the maximum likelihood estimators, and since betahat.gif, and chat.gif are positive parameters, ln (betahat.gif) and ln (chat.gif) can then be treated as normally distributed. After performing this transformation, the bounds on the parameters can be estimated from:

6.21.1.gif

Also:

6.21.2.gif

and:

6.21.3.gif

The variances and covariances of β, B and C are estimated from the local Fisher Matrix (evaluated at betahat.gif, bhat.gif, chat.gif, as follows:

6.21.4.gif

Confidence Bounds on Reliability

The reliability function for the Arrhenius-Weibull (ML estimate) is given by:

6.22.1.gif

or:

6.22.2.gif

Setting:

6.22.3.gif

or:

6.22.4.gif

The reliability function now becomes:

6.22.5.gif

The next step is to find the upper and lower bounds on uhat2.gif:

6.22.24.gif(24)

6.22.25.gif(25)

where:

6.22.6.gif

or:

6.22.7.gif

The upper and lower bounds on reliability are:

6.22.8.gif

where uU and uL are estimated from Eqns. (24) and (25).

Confidence Bounds on Time

The bounds on time for a given reliability are estimated by first solving the reliability function with respect to time:

6.23.1.gif

or:

6.23.2.gif

where uhat2.gif = ln that.gif.

The upper and lower bounds on u are estimated from:

6.23.26.gif(26)

6.23.27.gif(27)

where:

6.23.28.gif

or:

6.23.29.gif

The upper and lower bounds on time can then found by:

6.23.30.gif

where uU and uL are estimated using Eqns. (26) and (27).

Approximate Confidence Bounds for the Arrhenius-Lognormal

Bounds on the Parameters

The lower and upper bounds on B are estimated from:

6.31.1.gif

Since the standard deviation, otdash2.gif and the parameter C are positive parameters, ln(otdash2.gif) and ln(C) are treated as normally distributed. The bounds are estimated from:

6.31.2.gif

and:

6.31.3.gif

The variances and covariances of B, C and otdash.gif are estimated from the local Fisher Matrix (evaluated at bhat.gif, chat.gif, otdash2.gif, as follows:

6.31.5.gif

6.31.4.gif

Bounds on Reliability

The reliability of the lognormal distribution is:

6.32.1.gif

Let zhat.gif(t, V; B, C, OT.gif) = eqn1.gif, then eqn. 2.gif.

For t = Tdash2.gif, zhat.gif = eqn. 3.gif and for t = oo.gif, zhat.gif = oo.gif. The above equation then becomes:

6.32.2.gif

The bounds on z are estimated from:

6.32.3.gif

where:

6.32.4.gif

or:

6.32.5.gif

The upper and lower bounds on reliability are:

6.32.6.gif

Confidence Bounds on Time

The bounds around time, for a given lognormal percentile (unreliability), are estimated by first solving the reliability equation with respect to time, as follows:

6.33.1.gif

where:

6.33.2.gif

and:

6.33.3.gif

The next step is to calculate the variance of Tdash2.gif (V; bhat.gif, chat.gif, otdash2.gif):

6.33.4.gif

or:

6.33.5.gif

The upper and lower bounds are then found by:

6.33.6.gif

Solving for TU and TL yields:

6.33.7.gif

See Also:
Arrhenius Relationship


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